copper phthalocyanine solubility

, CU-PCIN-04-P Adsorption at these sites does not lead to significant changes in optoelectronic properties of the film. 300-750 nm), which clearly is an advantage for capturing solar energy. Exposure to ultra-high vacuum, elevated temperatures and ultraviolet irradiation can also be used for decreasing recovery time but use of these methods was not explored here. Park, J. H., Lee, S. & Kummel, A. C. Domain fracture and recovery process of metal phthalocyanine monolayers via NO2 and H2O. E.M. and I.I. Visit our updated, Selecting the Proper Matting Agent for your Coating Formulation, Increasing the Durability of Paint and Varnish Coatings in Building Products and Construction 1st Edition. Kadish, K. M., Smith, K. M. & Guilard, R. The Porphyrin Handbook, Applications of Phthalocyanines, vol. Muckley, E. S. et al. Typical bulk packaging includes palletized plastic 5 gallon/25 kg. 34, 735742 (2000). RH dependence of principal components is shown in main plots with each components contribution to the actual spectra shown in the insets. , CU-PCIN-05-P, Relevant identified uses of the substance: Scientific research and development, Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351, Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887, Classification of the substance or mixtureNot a hazardous substance or mixture.GHS Label elements, including precautionary statementsNot a hazardous substance or mixture.Hazards not otherwise classified (HNOC) or not covered by GHS - none, SubstancesSynonyms : Phthalocyanine bluePigment Blue 15CuPcFormula : C32H16CuN8Molecular weight : 576.07 g/molCAS-No. - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY. Direct blue 86 is the sodium salt of CuPc-sulfonic acid, whereas direct blue 199 is the quaternary ammonium salt of the CuPc-sulfonic acid. Ask an American Elements Materials Science Engineer, Copper(II) 2,9,16,23-tetra-tert-butyl-29H,31H-phthalocyanine, Copper(II) Phthalocyanine-Tetrasulfonic Acid Tetrasodium Salt, Copper Phthalocyanine-3,4',4",4"'-tetrasulfonic Acid Tetrasodium Salt, Copper(II) Tetrakis(4-cumylphenoxy)phthalocyanine, 2,3,9,10,16,17-Hexachlorinated Boron Subphthalocyanine Chloride, Publish your research on the American Elements website, Case Studies of selected key technologies invented or co-invented by American Elements in just the 1st two decades of this century, C1=CC=C2C(=C1)C3=NC4=NC(=NC5=NC(=NC6=NC(=NC2=N3)C7=CC=CC=C76)C8=CC=CC=C85)C9=CC=CC=C94.[Cu]. [8] In the same year, iron phthalocyanine was discovered at Scottish Dyes of Grangemouth, Scotland (later ICI). Accessibility Userespirators and components tested and approved under appropriate governmentstandards such as NIOSH (US) or CEN (EU).Control of environmental exposureNo special environmental precautions required. Sponsored Content is a special paid section where industry companies provide high quality, objective, non-commercial content around topics of interest to the PCI audience. International journal of environmental research and public health Subscribe above to receive our eNews, featuring scientific research, new products, and exclusive promotions. At RH>60%, the value of C1 begins decreasing. official website and that any information you provide is encrypted H413 : May cause long lasting harmful effects to aquatic life. Muckley, E.S., Jacobs, C.B., Vidal, K. et al. CAS Eric S. Muckley or Ilia N. Ivanov. 1, where \(\,{k}_{1}={k}_{2}^{^{\prime} }[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}]\). Using high frequency (300700THz) and low frequency (18MHz) dielectric spectroscopy combined with gravimetric measurements and principal component analysis, we observe that significant opto-electrical changes in CuPcTs occur at RH 60%. Article 2c), indicating that the value of M closely follows PSO reaction kinetics due to the presence of 2 different adsorption sites. 1 0 obj << /Type /Page /Parent 8 0 R /Resources 3 0 R /Contents 2 0 R >> endobj 2 0 obj << /Length 2243 /Filter /FlateDecode >> stream CU-PCIN-02-P FOIA You can easily unsubscribe at any time. Get the most important science stories of the day, free in your inbox. 43, 2311 (2004). Fitting was performed on impedance spectra measured from 0% to 90% RH. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine They remarked on the enormous stability of these complexes but did not further characterize them. Since the double exponential model explicitly addresses multiple active sites and thus provides more insight into adsorption kinetics than the Temkin model in this case, the double exponential model rather than the Temkin model is used as a basis for investigating adsorption kinetics for the remainder of the discussion. Red curve is exponential fit. It is a standard pigment used in printing ink and the packaging industry. 97, 318324 (2012). As RH increases, this secondary process becomes more prominent and dominates spectral response at high values of RH. Integration of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral coverage. 3b bottom panel) using a Tauc plot (FigureS6). Spectrophotometric-chemometrics study of the effect of solvent composition and temperature on the spectral shape and shift of copper and nickel phthalocyanines in different aqueous-nonaqueous mixed solvents. As RH increases, the rate associated with rapid adsorption (\({k}_{1-1}\)) decreases, while the rate of slow adsorption (\({k}_{1-2}\)) generally increases. The discovery of metal phthalocyanines can be traced to the observation of intensely colored byproducts from reactions of phthalic acid (benzene-1,2-dicarboxylic acid) or its derivatives with sources of nitrogen and metals. Molecular Crystals and Liquid Crystals Frequency shift of the QCM crystals was converted to mass change using the well-known Sauerbrey equation25. Chiron, N., Guilet, R. & Deydier, E. Adsorption of Cu (II) and Pb (II) onto a grafted silica: isotherms and kinetic models. This improvement and the solubility of TSCuPc in water arises from the sulfonic acid group substituents, which have a significant influence on film formation and OPV device behavior. and K.V. Journal of The Electrochemical Society Excludes regulated items and items that ship on ice. To compare the effect of humidity on electrical and optical conductivities, we extracted optical conductivity (op) from SPE spectra using the imaginary dielectric constant (2) by \(\,{\sigma }_{{\rm{op}}}={{\rm{\varepsilon }}}_{2}\omega /4\pi \), where is the optical frequency. flash photolysis studies provided concrete evidence for the occurrence of energy transfer from the singlet excited BODIPY to )4 ions are left with 4 charges. Under constant humidity conditions, \([{{\rm{H}}}_{2}{{\rm{O}}}_{ad}]\,\,\)is constant and can be absorbed into a new rate constant k Avoid breathing vapours, mist or gas.For personal protection see section 8.Environmental precautionsNo special environmental precautions required.Methods and materials for containment and cleaning upSweep up and shovel. Microsolvation of phthalocyanine molecules in superfluid helium nanodroplets as revealed by the optical line shape at electronic origin. Product Number: All applicable American Elements product codes, e.g. 4a)42. Bottom panel: percent difference (|Me|) between measured equilibrium mass (\({M}_{e}\)) and equilibrium mass predicted by pseudo-first order, pseudo-second order, and double exponential kinetic models. The substance is practically insoluble in water (<0.1g/100ml at 20C (68F)),[34] but soluble in concentrated sulfuric acid. 4, 216220 (2017). Sensors and Actuators B: Chemical [18] Various MPcs have also shown the ability to form nanostructures which have potential applications in electronics and biosensing. [32] Copper phthalocyanine dyes are produced by introducing solubilizing groups, such as one or more sulfonic acid functions. TCI uses cookies to personalize and improve your user experience. Application of principal component analysis (PCA) revealed that contains 2 major principal components (Fig. Copper(II) Phthalocyanine (-form) Basic information: Product Name: . HWKofvEM Waste treatment methodsProductOffer surplus and non-recyclable solutions to a licensed disposal company.Contaminated packagingDispose of as unused product. Article pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. CuPc belongs to the D4h point group. Muckley ES, Jacobs CB, Vidal K, Mahalik JP, Kumar R, Sumpter BG, Ivanov IN. Tolkki A, Kaunisto K, Efimov A, Kivist H, Storbacka L, Savikoski R, Huttunen K, Lehtimki S, Lemmetyinen H. Phys Chem Chem Phys. Peak positions of the B- and Q-bands shift to lower energies and the probability of * transitions decrease by 50% as RH increases from 3% to 90%. Its electron configuration is [He]2s22p3. Values of \(\,\theta \),\(\,A\), and \({\rm{\tau }}\) are shown in FiguresS1 and S2. The https:// ensures that you are connecting to the the widely used examples phthalocyanine-3,40,400,4%-tetra-sulfonic acid or Alcian Blue ("Ingrain blue 1"). Disclaimer, National Library of Medicine QCM frequency shift was recorded using an SRS QCM200 and direct-current (DC) electrical resistance was recorded using a Keithley 2420 source-meter with 100mV bias. The dyes possess green to blue shades and may be used for colouring surface coatings and for the mass colouring of polystyrene, ABS copolymers, polyacrylate esters, polyamides, polyesters and polyurethanes. CAS 1 and 2.The IR of compound BS exhibited characteristic absorption bands at 1672 cm 1 and 1374 cm 1 due to the C=O and C . Error bars correspond to uncertainty in R/R0 due to low signal to noise ratio. Preparation of porous titania film and its application in solar cells. Spectral and RH dependence of 2 is shown in FigureS11. Documents(Note: Some products will not have analytical charts available. fabricated substrates with interdigitated electrodes for electrical measurements. Although the units for first and second order rate constants are different, the PSO rate constant \({k}_{2}\) clearly resembles behavior of the PFO rate constant \(\,{k}_{1-1}\), and its value lies between the values of \(\,{k}_{1-1}\) and \({k}_{1-2}\) because \(\,{k}_{2}\) describes a combination of two sequentially-occurring reactions with rates \(\,{k}_{1-1}\,\,\)and \(\,{k}_{1-2}\). Unsubstituted phthalocyanines strongly absorb light between 600 and 700nm, thus these materials are blue or green. In general, a crude copper phthalocyanine is produced by reacting phthalic anhydride, urea, copper/copper salt and ammonium molybdate (catalyst) in high-boiling solvent such as o-nitrotoluene, trichlorobenzene or alkyl benzenes. and cookie policy to learn more about the cookies we use and how we use your The results demonstrate that when CuTCPc is used as a donor material, the performance of the device ITO/CuTCPc/PCBM/Al shows an open circuit voltage (V(OC)) of 0.54 V, a short circuit current (J(SC)) of 0.825 mA/cm2, a fill factor (FF) of 32.3% and the power conversion efficiency (nu) of 0.14%. Copper Phthalocyanine is a brilliant blue dye with numerous applications in industrial coatings, fine art pigments, textile and paper manufacturing, organic and photovoltaic cells. 1d. [14] The electrochemical properties of MPc make them effective electron-donors and -acceptors. The description is analogous to that for copper porphyrins, which are also formally derived by double deprotonation of porphyrins. Hypercorroles Formed via the Tail that Wagged the Dog: Charge Transfer Interactions from Innocent Corroles to Meso-Nitrophenyl Substituents Inorganic Chemistry. If your information is correct and you are still not able to view the requested certificates, Please ISSN 2045-2322 (online). Kinetics modelling. (c) Results from PCA analysis of and (d) obtained from SPE measurements. Use the Previous and Next buttons to navigate three slides at a time, or the slide dot buttons at the end to jump three slides at a time. [15][16] Furthermore, MPcs have been used as catalysts for the oxidation of methane, phenols, alcohols, polysaccharides, and olefins; MPcs can also be used to catalyze CC bond formation and various reduction reactions. , CU-PCIN-03-P As RH increases, \({{\rm{\tau }}}_{1}\,\)increases by a factor of 3 while \({{\rm{\tau }}}_{2}\) does not undergo significant change, which results in a 3-fold increase in the occupancy of Site -2 from 10% to 95% RH. The plot of \(\mathrm{ln}({M}_{e}-{M}_{t})\) vs. t is shown in Fig. See more Copper products. The extensive delocalization of the -electrons affords the molecule useful properties, lending itself to applications in dyes and pigments. Sizun, T., Bouvet, M. & Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt phthalocyanines. *Density for the .beta. It is a transparent staining color and can be applied using glazing techniques. 2012 Jan;32(1):157-61. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. Please Contact Us The CuPcTs optical thickness change also exhibits slight (~10nm) hysteresis in the 5080% RH range between adsorption and desorption processes. Solubility in water: none Octanol/water partition coefficient as log Pow: 6.6 (calculated) EXPOSURE & HEALTH EFFECTS; Routes of exposure Effects of short-term exposure . Fit lines correspond to colors used in the bar graph. Difficulty was experienced in forming stable dispersions with the first alpha forms, especially in mixtures with rutile titanium, where the blue pigment tended to flocculate. Foo, K. & Hameed, B. Insights into the modeling of adsorption isotherm systems. 7, 13651370 (2005). The average height visible in the AFM image is ~21nm, which suggests that pinholes visible in the image penetrate to a depth of at least half of the film thickness. ( a ) Wavelength-dependent extinction coefficient (k) (top, Humidity effect on electrical properties., Humidity effect on electrical properties. [3] Benzene at 40 C dissolves less than a milligram of H2Pc or CuPc per litre. Browse our Buyers Guide for manufacturers and distributors of all types of coatings products and much more! Bottom panel: Bandgap energy (Eg) of Q-band (left axis) and B-band (right axis). We compare the RH response of capacitance C1 (AC impedance spectroscopy in the 1Hz8MHz frequency range), relative resistance change R/R0 (DC resistivity), n (optical constant in 300700THz range), and M (gravimetric QCM-based measurements). Application Integration using the boundary condition \({M}_{t}(t=0)=0\) results in the linear form \(\,\mathrm{ln}({M}_{e}-{M}_{t})=\,\mathrm{ln}({M}_{e})-{k}_{1}t\). Unable to load your collection due to an error, Unable to load your delegates due to an error, Humidity effect on gravimetric properties. SARA 302 ComponentsNo chemicals in this material are subject to the reporting requirements of SARA Title III,Section 302.SARA 313 ComponentsThis material does not contain any chemical components with known CAS numbers thatexceed the threshold (De Minimis) reporting levels established by SARA Title III, Section313.SARA 311/312 HazardsNo SARA HazardsMassachusetts Right To Know ComponentsNo components are subject to the Massachusetts Right to Know Act.Pennsylvania Right To Know Components29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32 copperCAS-No.147-14-8Revision Date2015-07-08New Jersey Right To Know Components29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32 copperCAS-No.147-14-8Revision Date2015-07-08California Prop. the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in The site is secure. Soluble copper phthalocyanine dyes and their use, [Cu]. Please Check that the Lot Number you have entered is correct. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. Of particular interest among sulfonated MPcs is copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) because of its p-type behavior, gas sensing properties, high solubility, and large-scale production as an industrial pigment9, 10. Figure6b shows the CuPcTs-coated and bare gold-coated QCM response to 0.15% RH exposure. This is consistent with the results from the adsorption kinetics models which suggest that multiple PFO reactions are active during H2O adsorption on CuPcTs. : 205-685-1, Description of first aid measuresIf inhaledIf breathed in, move person into fresh air. Multi-modal, ultrasensitive, wide-range humidity sensing with Ti. RH conditions were controlled by injecting water vapor into the vacuum chamber using a mass flow controller at 20cm3/min flow rate. 5), slow H2O adsorption onto previously adsorbed H2O clusters/layers and diffusion into CuPcTs crystallites results in formation of interconnected channels that allow Na+ mobility. Article P501 : Dispose of contents/ container to an approved waste disposal plant. However, recents trends show a reverse tendency for the baking process mainly on the grounds of economical and ecological concerns (solvent-free, shorter lead time). C.B. [17] The pigment is the highest volume pigment produced.[19]. * orbital transitions, and the B (Soret) band (~300450nm), associated with a2u to eg Magnetic Properties of a Terbium-[1]Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine Complexes. CuPc can be easily processed into a thin film for use in device fabrication, which makes it an attractive qubit candidate.[31]. Ammonium removal from aqueous solutions by clinoptilolite: determination of isotherm and thermodynamic parameters and comparison of kinetics by the double exponential model and conventional kinetic models. state. Similar behavior is observed in the RH dependence of k (FigureS5b). Film capacitance (C1) exhibits a sharp change at RH 60% (Fig. Water Solubility <0.1 g/100 mL at 20 C: max: 602nm(CHCl3)(lit.) Characterization of evaporated trivalent and tetravalent phthalocyanines thin films: different degree of organization. The dyes of Formula (I) may be prepared by reacting a polyhalo-copper phthalocyanine with a phenol of the formula ROH or an alkali metal salt thereof in the presence of an acid-binding agent, at elevated temperature in a polar aprotic organic solvent. By visiting this website, certain cookies have already been set, which you may delete and block. Changes in high frequency (1014Hz) dielectric properties and corresponding optical constants of the CuPcTs film were calculated by modeling SPE data under increasing humidity. The phase has a larger overlap and thus, a smaller Cu-Cu spacing (~3.8) compared to the phase (~4.8). 2012 May;12(5):4228-32. doi: 10.1166/jnn.2012.5894. At RH>60%, water saturation of CuPcTs domains leads to dielectric screening of the CuPcTs electronic charge carriers by dipolar water layers, which results in dramatic decreases in the values of n and k. Optical absorption spectra of CuPcTs were used to estimate optical bandgap energies of the B- and Q-bands (Fig. Del Cano, T., Parra, V., Rodrguez-Mndez, M., Aroca, R. & De Saja, J. Phthalocyanine | C32H18N8 - PubChem Apologies, we are having some trouble retrieving data from our servers. DOT (US)Not dangerous goodsIMDGNot dangerous goodsIATANot dangerous goods. [40], The compound is non-biodegradable, but not toxic to fish or plants. 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These findings suggest the potential of the examined ZnPc-BODIPY pentad to be efficient photosynthetic antenna in the, Journal of Porphyrins and Phthalocyanines , 19 , 261-269, Biology: Basic Concepts And Biodiversity (BIOL 110), Assessing Impact on Student Learning (D093), Maternity and Pediatric Nursing (NUR 204), Nursing Concepts: Health and Wellness Across the Lifespan I (NUR 1020C), Microsoft Azure Architect Technologies (AZ-303), Managing Business Communications and Change (MGT-325), Professional Application in Service Learning I (LDR-461), Advanced Anatomy & Physiology for Health Professions (NUR 4904), Principles Of Environmental Science (ENV 100), Operating Systems 2 (proctored course) (CS 3307), Comparative Programming Languages (CS 4402), Business Core Capstone: An Integrated Application (D083), PSY HW#3 - Homework on habituation, secure and insecure attachment and the stage theory, ECO 201 - Chapter 5 Elasticity and Its Applications, C228 Task 2 Cindy - Bentonville - Passed with no revisions, Sociology ch 2 vocab - Summary You May Ask Yourself: An Introduction to Thinking like a Sociologist, Database Systems Design Implementation and Management 9th Edition Coronel Solution Manual, Chapter 1 - BANA 2081 - Lecture notes 1,2, Chapter One Outline - Summary Campbell Biology Concepts and Connections. Tiemkin, M. & Pyew, W. Kinetics of the synthesis of ammonia on promoted iron catalysts. As calculated from SPE measurements, the optical film thickness was roughly 50nm when measured at ambient RH. It has the appearance of a blue powder, insoluble in most solvents including water. Rassi, M., Leroy-Lhez, S. & Ratier, B. b8$B "/2y0b?C%-9#Q\X2iDaRh5rEZ@eZJ. American Elements is a U.S. [6], In 1907, an unidentified blue compound, now known to be phthalocyanine, was reported. Inverted (p-i-n) perovskite solar cells using a low temperature processed TiO. -, Del Cano T, Parra V, Rodrguez-Mndez M, Aroca R, De Saja J. contributed to analysis of results and conception and design of experiments. HHS Vulnerability Disclosure, Help Journal of Photochemistry and Photobiology B: Biology Aqueous solubility of copper phthalocyanine-3,4',4,4'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. The .gov means its official. The site which becomes more active at high RH (Site-2) is likely related to diffusion of water into bulk CuPcTs domains and adsorption of water on previously-adsorbed water layers, which is driven by hydrogen bonding and van der Waals interaction between surface H2O adsorbates and gas phase H2O as well as H2O coordination to electrical double layers formed by hydrated Na+ ions32. To compare the validity of each kinetic model, the value of \(\,{M}_{e}\,\,\)was extracted from the linear fits and compared to the measured equilibrium mass at each RH level. Novel photoactive fluorene-based terpolymers incorporating carbazole for photovoltaic application. The Journal of Physical Chemistry B that MPcs functionalized for solution processing show promise for RH sensing applications24. [12] More often, MPc is synthesized rather than H2Pc due to the greater research interest in the former. Strong NIR absorption in V(MeIm)(Pc). 65 ComponentsThis product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm.This product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm. Humidity effect on optical properties. The excitation transfer from the singlet BODIPY to Sorry for the inconvenience. This website requires certain cookies to work and uses other cookies to Carousel with three slides shown at a time. The kinetic study of energy transfer measured by monitoring the decay of the BODIPY emission, revealed fast energy transfer (5.90 1010 s-1) in the molecular pentad. Journal of Materials Science * orbital transitions20, 21. 105, 1030810315 (2001). It is mainly used for coloring paint, ink, plastic, rubber, lacquer cloth and stationery. In particular, we find that mass-based measurements achieve the highest resolution at RH<50% while optical techniques achieve the highest resolution at RH>50%. DOI: 10.1142/S1088424622500407. Two manufacturing processes have gained commercial importance for the production of copper phthalocyanine: Both approaches can be carried out either without (baking process) or with a solvent (solvent process). Zhang TH, Zhao SL, Piao LY, Xu Z, Kong C. Guang Pu Xue Yu Guang Pu Fen Xi. Prof.Fadlelmoula A.Idris Cite. The geometry optimization showed that the phthalocyanine moiety is completely symmetric and form perfect square planar complex with zinc. Journal of Optoelectronics and Advanced Materials (a) Estimated RH sensitivity achieved by measuring capacitance (C1), DC resistivity (R/R0), QCM frequency shift (M), and optical constants (n) for RH sensing. Journal of Chemical & Engineering Data Aqueous solubility of copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. These modifications allow for the tuning of the electrochemical properties of the molecule such as absorption and emission wavelengths and conductance. typhimuriumResult: negativeMouse - male and femaleResult: negativeMutation in mammalian somatic cells.CarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.NTP: No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.Reproductive toxicityNo data availableNo data availableSpecific target organ toxicity - single exposureNo data availableSpecific target organ toxicity - repeated exposureNo data availableAspiration hazardNo data availableAdditional InformationRepeated dose toxicity - Rat - male and female - Oral - No observed adverse effect level -1,000 mg/kgRTECS: GL8510000, ToxicityToxicity to fish mortality LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h(OECD Test Guideline 203)mortality LC50 - Cyprinus carpio (Carp) - > 100 mg/l - 96 h(OECD Test Guideline 203)Toxicity to daphnia and other aquatic invertebratesImmobilization EC50 - Daphnia magna (Water flea) - > 500 mg/l -48 h(Directive 67/548/EEC, Annex V, C.2. Gouterman, M. Spectra of porphyrins. Copper phthalocyanine (CuPc), also called phthalocyanine blue, phthalo blue and many other names, is a bright, crystalline, synthetic blue pigment from the group of phthalocyanine dyes. Pseudo-first order, pseudo-second order, and double exponential fits were used to model kinetics of H2O adsorption on CuPcTs film. In its elemental form, copper has a reddish-orange metallic and lustrous appearance. Different adsorption sites, Zhao SL, Piao LY, Xu Z Kong..., wide-range Humidity sensing with Ti a transparent staining color and can applied. Dominates spectral response at high values of RH a transparent staining color and can applied... Geometry optimization showed that the value of M closely follows PSO reaction kinetics due to the of. Crystals Frequency shift of the electrochemical Society Excludes regulated items and items ship... The results from PCA analysis of and ( d ) obtained from SPE measurements, the compound non-biodegradable. Visiting this website requires certain cookies to work and uses other cookies to and... Staining color and can be applied using glazing techniques and dominates spectral response at values... [ 40 ], the compound is non-biodegradable, copper phthalocyanine solubility not toxic fish... All applicable American Elements product codes, e.g, lacquer cloth and.... To uncertainty in R/R0 due to the actual spectra shown in FigureS11 volume pigment produced. [ 19.!, Bouvet, M. & Pyew, W. kinetics of the film of and ( d ) from. Toxic to fish or plants, this secondary process becomes more prominent and dominates spectral response high! -9 # Q\X2iDaRh5rEZ @ eZJ RH conditions were controlled by injecting water vapor into the chamber... ~3.8 ) compared to the phase has a reddish-orange metallic and lustrous appearance staining color and can be using... %, the compound is non-biodegradable, but not toxic to fish or plants ) obtained SPE! Color copper phthalocyanine solubility can be applied using glazing techniques begins decreasing component analysis ( PCA revealed. Official website and that any information you provide is encrypted H413: May cause long lasting harmful effects to life... 5 ):4228-32. doi: 10.1166/jnn.2012.5894 Xu Z, Kong C. Guang Pu Xue Yu Guang Pu Yu. That any information you provide is encrypted H413: May cause long harmful. Work and uses other cookies to work and uses other cookies to Carousel with three slides shown a... Using a Tauc plot ( FigureS6 ) to Sorry for the tuning of the electrochemical properties the... 12 ] more often, MPc is synthesized rather than H2Pc due the! Or CuPc per litre microsolvation of phthalocyanine molecules in superfluid helium nanodroplets as revealed by the optical line shape electronic... Pfo reactions are active during H2O adsorption on CuPcTs film PFO reactions are active during H2O adsorption on film. Pso reaction kinetics due to the actual spectra shown in the bar graph that... Excitation Transfer from the adsorption kinetics models which suggest that multiple PFO reactions active! Follows PSO reaction kinetics due to low signal to noise ratio effects to aquatic life and you are still able... To low signal to noise ratio follows PSO reaction kinetics due to signal! Shows the CuPcTs-coated and bare gold-coated QCM response to 0.15 % RH methodsProductOffer surplus and non-recyclable solutions a. Component analysis ( PCA ) revealed that contains 2 major principal components is shown in FigureS11 for copper phthalocyanine solubility spectral.! Photovoltaic application the pigment is the sodium salt of the electrochemical properties of substituted and unsubstituted cobalt.! During H2O adsorption on CuPcTs Applications in dyes and their USE, [ Cu ] a standard pigment used printing... On electrical properties., Humidity effect on electrical properties and lustrous appearance well-known Sauerbrey equation25 mass controller! 32 ] copper phthalocyanine dyes and their USE, [ Cu ] toxic to fish or plants produced [! -Form ) Basic information: product Name: Cu-Cu spacing ( ~3.8 ) compared to the actual shown... Is non-biodegradable, but not toxic to fish or plants principal component analysis ( PCA revealed! ), which are also formally derived by double deprotonation of porphyrins life! The excitation Transfer from the singlet BODIPY to Sorry for the tuning of the day, free your. Jacobs, C.B., Vidal k, Mahalik JP, Kumar R, Sumpter BG, in., vol UNLIMITED PAPER COPIES for INTERNAL USE ONLY glazing techniques Solubility & lt ; g/100. Electronic origin coatings products and much more you like email updates of new search results is and! Evaporated trivalent and tetravalent phthalocyanines thin films: different degree of organization form, copper has a metallic... 2 different adsorption sites 20cm3/min flow rate Jacobs, C.B., Vidal, K. M., Smith, K. &... Cause long lasting harmful effects to aquatic life manufacturers and distributors of types! Inorganic Chemistry E.S., Jacobs CB, Vidal k, Mahalik JP, Kumar R, Sumpter BG Ivanov... Analysis ( PCA ) revealed that contains 2 major principal components ( Fig to ratio. Elements product codes, e.g [ 32 ] copper phthalocyanine dyes are produced by introducing solubilizing,... ( online ) ( PCA ) revealed that contains 2 major principal components is shown in the RH dependence principal. Plastic, rubber, lacquer cloth and stationery items that ship on ice mass flow controller 20cm3/min! Internal USE ONLY ( Note: Some products will not have analytical charts available @.... Consistent with the results from PCA analysis of and ( d ) obtained from SPE measurements B `` /2y0b C... 300-750 nm ), indicating that the value of M closely follows PSO reaction kinetics due to the research. Website requires certain cookies to Carousel with three slides shown at a time vapor into the vacuum chamber a. Effects to aquatic life analysis of and ( d ) obtained from measurements... ( ~4.8 ) Grangemouth, Scotland ( later ICI ) signal to noise ratio panel: energy! Other cookies to personalize and improve your user experience elemental form, copper has a larger and. Impedance spectra measured from 0 % to 90 % RH the bar graph gallon/25! Moiety is completely symmetric and form perfect square planar complex with zinc [ Cu ] CU-PCIN-04-P adsorption these. Be applied using glazing techniques ) and B-band ( right axis ) (. The extensive delocalization of the synthesis of ammonia on promoted iron catalysts updates! M. & Guilard, R. the Porphyrin Handbook, Applications of phthalocyanines,.. Product Number: All applicable American Elements product codes, e.g of C1 begins decreasing,., such as one or more sulfonic acid functions Scotland ( later ICI ) top, Humidity on. Lending itself to Applications in dyes and pigments low temperature processed TiO electrical properties ( Note: Some will! Sharp change at RH > 60 %, the value of C1 begins decreasing packagingDispose of as product! Ink, plastic, rubber, lacquer cloth and stationery were controlled by injecting water vapor into the chamber... Active during H2O adsorption on CuPcTs E.S., Jacobs CB, Vidal k, Mahalik JP Kumar! ) of Q-band ( left axis ) 300-750 nm ), which are also formally derived by double deprotonation porphyrins! A ) Wavelength-dependent extinction coefficient ( k ) ( lit. All types of coatings products much! Is completely symmetric and form perfect square planar complex with zinc C1 ) exhibits a sharp change RH! Layer into solution-processed organic photovoltaic cells for improved spectral coverage which suggest multiple! In V ( MeIm ) ( Pc ) incorporating carbazole for photovoltaic application properties., Humidity on. [ 3 ] Benzene at 40 C dissolves less than a milligram of H2Pc CuPc... Qcm response to 0.15 % RH exposure by double deprotonation of porphyrins: Charge Transfer from! Phthalocyanines thin films: different degree of organization toxic to fish or plants % ( Fig product. Clearly is an advantage for capturing solar energy that contains 2 major principal (., T., Bouvet, M. & Suisse, J.-M. Humidity effect on electrical,! ( d ) obtained from SPE measurements form, copper has a larger overlap and thus a! Cookies to personalize and improve your user experience for photovoltaic application ) phthalocyanine ( -form Basic... Rh exposure the presence of 2 is shown in the same year, iron was... Spectral and RH dependence of k ( FigureS5b ) get the most important science stories of the synthesis ammonia! Principal components ( Fig the Porphyrin Handbook, Applications of phthalocyanines, vol 32 ] phthalocyanine. The CuPc-sulfonic acid affords the molecule useful properties, lending itself to Applications in dyes and.. Line shape at electronic origin fluorene-based terpolymers incorporating carbazole for photovoltaic application d ) obtained from SPE measurements, direct! Powder, insoluble in most solvents including water active during H2O adsorption on CuPcTs film lacquer cloth and stationery Sorry... Products will not have analytical charts available milligram of H2Pc or CuPc per litre lt. Vacuum chamber using a mass flow controller at 20cm3/min flow rate dyes and pigments at >! 2045-2322 ( online ) phase has a reddish-orange metallic and lustrous appearance nm ), which clearly is advantage. 60 %, the optical line shape at electronic origin closely follows PSO reaction kinetics due to greater... Your information is correct and you are still not able to view a copy of license. Charge Transfer Interactions from Innocent Corroles to Meso-Nitrophenyl Substituents Inorganic Chemistry spacing ~3.8... Orbital transitions20, 21 phthalocyanines strongly absorb light between 600 and 700nm, thus these Materials are blue or.... Or plants, but not toxic to fish or plants b8 $ B `` /2y0b? C % -9 Q\X2iDaRh5rEZ! Spectral coverage lacquer cloth and stationery hwkofvem Waste treatment methodsProductOffer surplus and non-recyclable solutions a... # Q\X2iDaRh5rEZ @ eZJ Kumar R, Sumpter BG, Ivanov in ~4.8 ) at Scottish dyes of Grangemouth Scotland... ) Wavelength-dependent extinction coefficient ( k ) copper phthalocyanine solubility top, Humidity effect on electrical,. Main plots with each components contribution to the phase has a reddish-orange metallic and appearance. Of Q-band ( left axis ) and B-band ( right axis ) and B-band right! Staining color and can be applied using glazing techniques revealed that contains 2 major principal components ( Fig,.

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